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DTIC AD0671550: TERNARY PHASE EQUILIBRIA IN TRANSITION METAL-BORON-CARBON-SILICON SYSTEMS. PART 1. BINARY SYSTEMS. VOLUME 13. THE ZIRCONIUM-SILICON AND HAFNIUM-SILICON SYSTEMS
The zirconium-silicon and hafnium-silicon binary systems were investigated by means of Debye-Scherrer X-ray analysis, metallography, melting points, differential analysis techniques, and chemical analysis. Both silicide systems contain a D8(8)-type phase which is stabilized by trace impurities of oxygen and nitrogen. The binary phases present are: Zr4Si, Zr2Si, Zr3Si2, Zr5Si4, alpha- and Beta-ZrSi, and ZrSi2; in the hafnium system: Hf2Si, Hf3Si2, Hf5Si4, and HfSi2. The ZrSi phase undergoes an allotropic transformation at 1550C; the high temperature form is of the CrB type while the low temperature crystal structure is of the FeB type. Complete phase diagrams from 1100C up to melting are given.
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Ebook · DTIC AD0671550: TERNARY PHASE EQUILIBRIA IN TRANSITION METAL-BORON-CARBON-SILICON SYSTEMS. PART 1. BINARY SYSTEMS. VOLUME 13. THE ZIRCONIUM-SILICON AND HAFNIUM-SILICON SYSTEMS · Defense Technical Information Center · Internet Archive
DTIC Archive · Brukl, C E · AEROJET-GENERAL CORP SACRAMENTO CA MATERIALS RESEARCH LAB · *HAFNIUM ALLOYS · *REFRACTORY MATERIALS · *SILICON ALLOYS · *ZIRCONIUM ALLOYS · CHEMICAL ANALYSIS · CRYSTAL STRUCTURE · DIFFERENTIAL THERMAL ANALYSIS